Glass Beads Safety Data
Glass Beads
Provided below is all the current safety data we have on our  dh glass beads.
Identification
Product identifier -  dh glass beads
Synonyms - Glass Beads, GLASS, OXIDE
Recommended use - Traffic Markings
Recommended restrictions - None known
Manufacturer/Supplier -  LANGFANG DAOHONG GLASS BEADS CO.,LTD

DH  Identification

GHS CLASSIFICATION
Classification of the substance or mixture	Not classified as hazardous according to GHS standards.
Health Hazards:	The substance does not meet the criteria for classification.
Environmental
Acute Toxicity	None Known.
Chronic Toxicity	None Known.
Physical hazards	The substance does not meet the criteria for classification.
Label elements
Signal word	NONE
Hazard statements	The substance does not meet the criteria for classification.
Precautionary statements
Prevention	P201+P202: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.  P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response	P304: IF INHALED: Remove person to fresh air and Keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.  P305: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.  P302+P352+P363: IF ON SKIN: Wash with plenty of water. Wash contaminated clothing before reuse.
Storage	P402+P403+P404: Store in a dry place. Store in a well ventilated place.  Store in a closed container.
Disposal	P501: Dispose of contents/ container to an approved waste disposal plant.
Hazard(s) not otherwise classified (HNOC)	Spilled material is extremely slippery.

 
Composition/information on ingredients

Chemical Name (Common / Other Names)
Glass. Oxides, Chemicals	65997-17-3	>99%

The criteria for listing components in the composition are as follows: Carcinogens are listed when present at 0.1% or greater; components, which are otherwise hazardous according to OSHA, are listed when present at 1.0% or greater. Non-hazardous components may be listed at 3.0% or greater if not 
First-aid measures

Inhalation	If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Skin contact	Wash off with soap and plenty of water. Remove Contaminated Clothing and shoes. Get medical attention if Irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye contact	Flush eyes with water as a precaution.
Ingestion	Never give anything by mouth to an unconscious person. Rinse mouth with water.
Chronic (long-term) effects	Not known.

Fire-fighting Measures

Suitable extinguishing media	This material is compatible with all extinguishing media.  Extinguish preferably with dry chemical, foam or water spray.
Unsuitable extinguishing media	None known.
Specific hazards arising from the chemical	Silicon oxides
Special protective equipment and precautions for firefighters	A self-contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Spilled material is extremely slippery. Wear rubber boots with slip-resistant soles.

Accidental release measures

Personal precautions, protective equipment and emergency procedures	Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Spilled material can be very slippery. Wear rubber boots with slip-resistant soles. See Section 8 of the SDS for Personal Protective Equipment.
Methods and materials for containment and cleaning up	Collect mechanically and dispose of according to Section 13. Transfer to a lidded container for disposal or recovery. Avoid dust generation. Ensure adequate ventilation. Do not walk through spilled material.

Handling and storage

Precautions for safe handling	Avoid contact with skin, eyes, and clothing. Wash hands before eating, drinking or smoking.  Avoid accumulation of dust. Use only in well-ventilated areas.
Conditions for safe storage, including any incompatibilities	Store in the original container in a cool, dry, well-ventilated area. Keep containers tightly sealed. Incompatible Materials: Dissolves in hydrofluoric acid.

Exposure controls/personal protection
Occupational exposure limits

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Components	Type	Value
Glass. Oxides, Chemicals (CAS No. 65997-17-3)	PEL(TWA)	15 mg/m3 (total dust), 5 mg/m3 (respirable)

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components	Type	Value
Glass. Oxides, Chemicals (CAS No. 65997-17-3)	8-hour TWA	5 mg/m3 (respirable)

US. OSHA Table Z-3 Mineral dusts (29 CFR 1910.1000)

Components	Value
Respirable fraction greater than 5% SiO2	%SiO2 + 2 mg/m3

US. OSHA Table Z-2 (29 CFR 1910.1000)
None of the components in this product are listed.
US. ACGIH Threshold Limit Values

Components	Type	Value
Glass. Oxides, Chemicals  (CAS No. 65997-17-3)	TLV	10 mg/m3 (inhalable)  3 mg/m3 (respirable)

 US. NIOSH: Pocket Guide to Chemical Hazards

Components	Type	Value
Glass. Oxides, Chemicals  (CAS No. 65997-17-3)	REL (TWA)	TWA 3 fibers/cm3  (fibers ≤ 3.5 μm in diameter  & ≥ 10 μm in length)  TWA 5 mg/m3 (total)

Appropriate engineering controls 
Individual protection measures, such as personal protective equipment

Eye/face protection - Avoid eye contact. Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection - Wear protective gloves. Suitable gloves can be recommended by the glove supplier.
Other - Wear suitable protective clothing.
Respiratory protection - Avoid breathing dust. Assess exposure concentrations of all materials involved in the workplace. If concentrations exceed the exposure limits listed in Exposure Guidelines or irritation or other symptoms experienced, follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149.

General hygiene considerations - Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Physical and chemical properties
Appearance
Physical state - Solid
Form - Glass bead
Color - Colorless
Odor - Odorless
Odor threshold (ppm) - Not Available
pH - No data available
Melting point/freezing point - Approximately 730º C (1346°F)
Initial boiling point and boiling range - No data available
Flashpoint - Not combustible
Evaporation rate - No data available
Flammability (solid, gas)
Flammability limit - lower (%) – No data available
Flammability limit - upper (%) – No data available
Explosive limit - lower (%) - No data available
Explosive limit - upper (%) - No data available
Vapor pressure - No data available
Vapor density - No data available
Relative density (specific gravity) - 2.4 - 2.6
Refractive index -≥1.5
Spherical beads (%) - >70
Solubility (water) - Insoluble
Partition coefficient (n-octanol/water) - No data available
Auto-ignition temperature - No data available
Decomposition temperature - No data available
Viscosity - No data available
Volatile Organic Compounds - No data available
Sieve Analysis
BS6088,1981UK

CLASS A istribution and Roundness

Sieve No.	Quantity on Sieve%	Roundness in min	Defect Beads in max
1.18	0-3	70% Ours can reach to 75% up	30% Ours can be 25% below
850µm	5-20
425µm	65-95
425µm	0-15

CLASS B Distribution and Roundness

Sieve No.	Quantity on Sieve%	Roundness in min	Defect Beads in max
850µm	0-5	80% Ours can reach to 85% up	20% Ours can be 15% below
600µm	5-20
300µm	30-75
180µm	10-30
<180µm	0-15

 
 
 
Stability and Reactivity
Reactivity - Not generally reactive under normal conditions
Chemical stability - Stable under recommended storage conditions.
Possibility of hazardous reactions - None under normal processing
Conditions to avoid - No data available
Incompatible materials - Dissolves in hydrofluoric acid
Hazardous Decomposition Products - Hazardous decomposition products formed under fire conditions. - silicon oxides. Other decomposition products - No data available
Toxicological information
Information on likely routes of exposure
Ingestion - Do not ingest. May cause discomfort if swallowed.
Inhalation - Dust may irritate respiratory system. Prolonged inhalation may be harmful.
Skin contact - Dust or powder may irritate the skin.
Eye contact - Particulates may cause irritation to the eyes.
Symptoms related to the physical,
chemical & toxicological characteristics - Dusts may irritate the respiratory tract, skin and eyes.
Delayed & immediate effects & chronic effects from short-& long-term exposure - Causes eye irritation. May cause respiratory irritation. May cause transient irritation.
Numerical measures of toxicity

Components	Test	Species	Test Results
Glass, Oxides, Chemicals (CAS No. 65997-17-3)	Oral LD50 Inhalation LC50	Rat Rat	> 2000 mg/kg  No data

Skin corrosion/irritation - May be irritating to the skin.
Serious eye damage/eye irritation - May be irritating to eyes.
Respiratory or skin sensitization
Respiratory sensitization - No data available.
Skin sensitization - No data available.
Germ cell mutagenicity - No data available.
Carcinogenicity 
IARC Monographs. Overall Evaluation of Carcinogenicity- Not classifiable as to carcinogenicity to humans
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) - Not listed.
Reproductive toxicity - No data available.
Specific target organ toxicity – single exposure - Not classified.
Specific target organ toxicity – repeated exposure - Not classified.
Aspiration hazard - No data available.
Ecological information
Numerical measures of toxicity 

Components	Test	Species	Test Results
Glass, Oxides, Chemicals (CAS No. 65997-17-3)	Crustacea EC50	Water flea (Daphnia magna)	>1,000 mg/l 72 Hours

Toxicity - No known reports of ecotoxicity to the environment.
Persistence and degradability - Persistent but inert in aquatic systems.
Bioaccumulative potential - The product will not bioaccumulate up the food chain.
Mobility in soil - Sinks in water. Insoluble in water.
Results of PBT and vPvB Assessment - No data.
Other adverse effects - None known.
Disposal considerations
Disposal instructions - Disposed material is not a hazardous waste. Disposal should be in accordance with local, state or national legislation.
Hazardous waste code

US RCRA Hazardous Waste U List

Not applicable

Contaminated packaging - Container must be disposed of in accordance with local, state and national regulations. Containers must not be punctured or destroyed by burning, even when empty.
Transport information

DOT, IATA, and IMDG	Not regulated as dangerous goods.
UN number	None
Environmental hazards
Marine pollutant	None
Special precautions for user	Read safety instructions, SDS and emergency procedures before handling. Spilled material is extremely slippery:

Regulatory information
US federal regulations 
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) - Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) - Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4) - None of the components in this product are regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA Title III Classification:

Hazard Categories	Immediate Hazard: No	Pressure Hazard: No
	Delayed Hazard: No	Reactivity Hazard: No
	Fire Hazard: No

SARA 302 Extremely hazardous substance - None of the components in this product are listed. No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 304 Emergency release notification - Not regulated. 
SARA 311/312 Hazardous chemical - No SARA Hazards.
SARA 313 (TRI reporting) - This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List - No components in this product are listed.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) - No components in this product are listed.
Safe Drinking Water Act (SDWA) - No components in this product are listed.

US State regulations
Massachusetts RTK - Substance List  Glass, Oxide, Chemicals (CAS 65997-17-3)  New Jersey Worker and Community Right-to-Know Act  Glass, Oxide, Chemicals (CAS 65997-17-3)  Pennsylvania Worker and Community Right-to-Know Law  Glass, oxide, Chemicals, non-fibrous , CAS No. 65997-17-3
US. California Proposition 65  Carcinogens & Reproductive Toxicity (CRT): Substance List	This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
United States & Puerto Rico	Toxic Substances Control Act (TSCA) Inventory	Yes

*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the
governing country(s).
Other information, including date of preparation or last revision 

Issue Date	07-09-2019
Revision date
Version #	1

 Disclaimer: The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal
and release and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in any process, unless specified
in the text. Because of conditions of use are beyond our control, no guarantee, representation or warranty expressed or implied is
made. We urge each customer or recipient of this SDS to study it carefully to become aware of and understand the potential
hazards associated with the product. Customary precautionary measures for handling chemicals should be followed.
Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to
ensure that his activities comply with all federal, state, provincial or local laws. Since conditions for use of this product are not
under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this
product. Any use of the product not in conformance with this SDS or in combination with any other product or process is the
responsibility of the user.Langfang Daohong Glass Beads Co., Ltd for further information.
 
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